Publications



57	Association of Pyramidal Boron Lewis Superacids with Pyridines: Bending 2,4,6-Collidine with the 10-Sulfonium-9-boratriptycene, Osi, A., Niessen, N., Mahaut, D., Champagne, B., Chardon, A., Tumanov, N., Wouters, J., Berionni, G., Z. Anorg. Allg. Chem. 2023, 649, e202300066. [Download]
56	A focus on anionic boron anthracenes and triptycenes as entry point toward B-doped polyaromatic materials and Lewis acids, G. Berionni, Chem. Sci., 2023,14, 5241-5242 [Download]
55	From Proton to Boron: The Lewis Analogs of Protonated Brønsted Super Acids, Osi, A., Tumanov, N., Fusaro, L., Wouters, J., Berionni, G., Chardon, A., Chem. Eur. J. 2023, e202301146 [Download] Dedicated to Prof. Alain Krief for his 80^th birthday.
54	Regioselective Transition-Metal Free Arenes C-H Borylations: From Directing Groups to Borylation Template Reagents, G. Berionni, Angew. Chem. Int. Ed. 2022, 61, e202210284. [Download]
53	Reprogramming Main-Group Compounds: Toward New Superelectrophilic and Superacidic Catalysts, G. Berionni, Chimie Nouvelle, 2022, 139, 27-29. DOI: 10.52809/cn2022.nxmn2068 [download]
52	A Selenium Substituted Pyramidal 9-Boratriptycene Lewis Acid, A. Osi, N. Tumanov, J. Wouters, A. Chardon, G. Berionni, Synthesis 2022, online, DOI: 10.1055/a-1840-5680. [download]
51	9-phosphatriptycene derivatives: from their weak basicity to their application in frustrated Lewis pair chemistry D. Mahaut, G. Berionni, B. Champagne, J. Phys. Chem. A 2022, 126, 18, 2794–2801 [download]
50	Frustrated Lewis pair-catalyzed hydrogenation of unactivated alkenes with sterically hindered 9-phosphatriptycenes D. Mahaut, B. Champagne, G. Berionni, 2022, ChemCatChem 2022,14, e202200294. [download]
49	Taming the Lewis Superacidity of Non-Planar Boranes: C-H Bond Activation and Non-Classical Binding Modes at Boron A. Osi, D. Mahaut, N. Tumanov, L. Fusaro, J. Wouters, B. Champagne, A. Chardon, G. Berionni. Angew. Chem. Int. Ed. 2022, 61, e202112342. [download]
48	Young Career Focus presents Guillaume Berionni, Synform, 2021, 159-161 [download]
47	Future Prospects in Boron Chemistry: Boron Lewis Acids in Perspective Chem. Syn. 2021, 1:10. DOI: 10.20517/cs.2021.11 [download]
46	Rational Development of a Metal-Free Bifunctional System for the C-H Activation of Methane: A Density Functional Theory Investigation D. Mahaut, A. Chardon, L. Mineur, G. Berionni, B. Champagne, ChemPhysChem 2021, 22, 1958–1966. [download]
45	Six-membered Rings with One Phosphorus Atom F. Rammal, V. Magné, G. Berionni, S. Lakhdar, Comprehensive Heterocyclic Chemistry IV, Elsevier, 2022, Volume 7, 685-717 (book chapter). [download]
44	Four-membered Rings with One Phosphorus, Arsenic, Antimony, or Bismuth Atom V. Magné, F. Rammal, G. Berionni, S. Lakhdar, Comprehensive Heterocyclic Chemistry IV, Elsevier, 2022, Volume 2, 335-362 (book chapter). [download]
43	*Sterically hindered ortho-substituted phosphatriptycenes as configurationally stable P-chirogenic triarylphosphines* L. Hu, D. Mahaut, N. Tumanov, J. Wouters, L. Collard, R. Robiette, G. Berionni, Dalton Trans. 2021, 50, 4772-4777 [download]
42	Triptycene Boronates, Boranes, and Boron Ate‐Complexes: Toward Sterically Hindered Triarylboranes and Trifluoroborates M. Gama, X. Antognini Silva, T-H. Doan, A. Osi, A. Chardon, N. Tumanov, J. Wouters, G. Berionni, Eur. J. Org. Chem. 2021, 1440–1445 [download]
41	Methylene Bridging Effect on the Structures, Lewis Acidities and Optical Properties of Semi Planar Triarylboranes T.-H. Doan, A. Chardon, A. Osi, D. Mahaut, N. Tumanov, J. Wouters, B. Champagne, G. Berionni, Chem. Eur. J. 2021, 27, 1736-1743. [download]
40	Non-planar Boron Lewis Acids Taking the Next Step: Development of Tunable Lewis Acids, Lewis Superacids and Bifunctional Catalysts A. Chardon, A. Osi, D. Mahaut, A. Ben Saida, G Berionni, Synlett. 2020, 31, 1639-1648. [download]
39	Controlled Generation of 9-Boratriptycene by Lewis Adduct Dissociation: Accessing a Unique Non-Planar Triarylborane A. Chardon, A. Osi, D. Mahaut, T.-H. Doan, N. Tumanov, J. Wouters, L. Fusaro, B. Champagne, G Berionni, Angew. Chem. Int. Ed. 2020, 59, 12402-12406. [download]
38	Pushing the Lewis Acidity Boundaries of Boron Compounds With Non-Planar Triarylboranes Derived from Triptycenes A. Ben Saida, A. Chardon, A. Osi, N. Tumanov, J. Wouters, A. I. Adjieufack, B. Champagne, G. Berionni, Angew. Chem. Int. Ed. 2019, 58, 16889–16893. [download]
37	Complementary Synthetic Approaches toward 9-Phosphatriptycene and Structure–Reactivity Investigations of Its Association with Sterically Hindered Lewis Acids L. Hu, D. Mahaut, N. Tumanov, J. Wouters, R. Robiette, G. Berionni, J. Org. Chem. 2019, 84, 11268−11274. [download]
36	The Halogen–Samarium Exchange Reaction: Synthetic Applications and Kinetics L. Anthore‐Dalion, A. D. Benischke, B. Wei, G Berionni, P. Knochel, Angew. Chem. Int. Ed. 2019, 58, 4046. [download]
35	Opening Up New Research Lines in Lewis Acid/Base Catalysis G. Berionni, L. Hu, A. Ben Saida, A. Chardon, M. Gama, A. Osi, D. Mahaut, X. Antognini Silva, Chimie Nouvelle, 2018, 128, 13. [download]
34	Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles A. D. Benischke, L. Anthore-Dalion, G. Berionni, P. Knochel, Angew. Chem. Int. Ed. 2017, 51, 16390-16394. [download]
33	Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles C. García-Ruiz, J. L.-Y. Chen, C. Sandford, K. Feeney, G. Berionni, H. Mayr, V. K. Aggarwal, J. Am. Chem. Soc., 2017, 139, 15324-15327. [download]
32	Mechanistic studies of formal thioboration reactions of alkynes A. Issaian, D. J. Faizi, J. O. Bailey, P. Mayer, G. Berionni, D. A. Singleton, S. A. Blum, J. Org. Chem.* 2017, 82, 8165-8178. [download]
31	Barbier continuous flow preparation and reactions of carbamoyllithiums for nucleophilic amidation M. A. Ganiek, M. R. Becker, G. Berionni, H. Zipse, P. Knochel, Chem. Eur. J.* 2017, 23, 10280-10284. [download]
30	Nucleophilicities and Lewis basicities of sterically hindered pyridines E. Follet, H. Zipse, S. Lakhdar, A. R. Ofial, G. Berionni, Synthesis* 2017, 49, 3495-3504. [special issue on the occasion of the 70th birthday of Professor Herbert Mayr] [download]
29	Superelectrophilicity in Michael-Type Reactions: Water Addition to 4-Nitrobenzodifuroxan S. Lakhdar,* G. Berionni, F. Terrier, Synthesis 2017, 49, 3453-3459. [special issue on the occasion of the 70th birthday of Professor Herbert Mayr] [download]
28	Reactivity-tuning in frustrated Lewis pairs: nucleophilicities and lewis basicities of sterically hindered phosphines E. Follet, P. Mayer, D. S. Stephenson, A. R. Ofial, G. Berionni, Chem. Eur. J.* 2017, 23, 7422-7427. [download]
27	Structures, Lewis acidities, electrophilicities, and protecting group abilities of phenyl-fluorenylium and tritylium ions. E. Follet, P. Mayer, G. Berionni, Chem. Eur. J.* 2017, 23, 623-630. [download][Selected as hot paper]
26	Nucleophilicity of alkyl zirconocene and titanocene precatalysts and kinetics of activation by carbenium ions and by B(C₆F₅)₃. G. Berionni, H. Kurouchi, L. Eisenburger, H. Mayr, Chem. Eur. J.* 2016, 22, 11196-11200. [download]
25	Scope and mechanisms of frustrated Lewis pair catalyzed hydrogenation reactions of electron-deficient C=C double bonds V. Morozova, P. Mayer, G. Berionni, Angew. Chem. Int. Ed.* 2015, 54, 14508-14512. [download]
24	Structure and Reactivity of Indolyl-methylium Ions: Scope and Limitations in Synthetic Applications E. Follet, G. Berionni, P. Mayer, H. Mayr, J. Org. Chem. 2015, 80, 8643-8656. [download]
23	Structure and Reactivity of Boron-Ate Complexes Derived from Primary and Secondary Boronic Esters K. Feeney, G. Berionni, H. Mayr, V. K. Aggarwal, Org. Lett. 2015, 17, 2614-2617. [download]
22	Fine-Tuning of the Nucleophilic Reactivities of Boron-Ate Complexes Derived From Aryl and Heteroaryl Boronic Esters G. Berionni, A. I. Leonov, P. Mayer, A. R. Ofial, H. Mayr, Angew. Chem. Int. Ed. 2015, 54, 2780-2783. [download]
21	Stereoselective Synthesis and Reactions of Secondary Alkyllithium Reagents Functionalized at the 3-Position K. Moriya, D. Didier, M. Simon, J. M. Hammann, G. Berionni, K. Karaghiosoff, H. Zipse, H. Mayr, P. Knochel, Angew. Chem. Int. Ed. 2015, 54, 2754-2757. [download]
20	Aromaticity evaluations of planar [6]radialenes Guillaume Berionni, Judy I. Chia Wu, Paul v R. Schleyer, Org. Lett.* 2014, 16, 6116-6119 [download]
19	Di- and Triarylmethylium Ions as Probes for the Ambident Reactivities of Carbanions Derived from 5-Benzylated Meldrum's Acid X. Chen, Y. Tan, G. Berionni, A. R. Ofial, H. Mayr, Chem. Eur. J. 2014, 20, 11069-11077. [download]
18	New In Situ Trapping Metalations of Functionalized Arenes and Heteroarenes with TMPLi in the Presence of ZnCl₂ and Other Metal Salts A. Frischmuth, M. FernÃ¡ndez, N. M. Barl, F. Achrainer, H. Zipse, G. Berionni, H. Mayr, K. Karaghiosoff, P. Knochel, Angew. Chem. Int. Ed. 2014, 53, 7928-7932. [download]
17	Mechanistic studies and quantification of the electrophilicity of aromatic triflones in sigma-complexation and S_NAr reactions N. El Guesmi, G. Berionni, B.H Asghar, J. Fluorine. Chem. 2014, 160, 41-47 [download]
16	Diastereoselective Synthesis of Open-Chain Secondary Alkyllithium Compounds and Trapping Reactions with Electrophiles G Dagousset, K Moriya, R Mose, G Berionni, K Karaghiosoff, P Knochel, Angew. Chem. Int. Ed. 2014, 53, 1425-1429. [download]
15	Electronic and solvent effects on kinetics of S_NAr substitution reactions of substituted anilines with 2,6-bis(trifluoromethanesulfonyl)-4-nitroanisole N. El Guesmi, G. Berionni, B.H Asghar, Monatsh. Chemie (Chemical Monthly) 2013, 144, 1537-1545. [download]
14	Electrophilic Aromatic Substitutions of Aryltrifluoroborates with Retention of the BF₃^- Group: Quantification of the Activating and Directing Effects of the Trifluoroborate Group G. Berionni, V. Morozova, M. Heininger, P. Mayer, P. Knochel, H. Mayr, J. Am. Chem. Soc. 2013, 135, 6317-6324. [download][Highlighted in Synfact, 2013, 9, 723]
13	Nucleophilicity parameters for designing transition metal-free C-C bond forming reactions of organoboron compounds G. Berionni, B. Maji, P. Knochel, H. Mayr, Chem. Sci. 2012, 3, 878-882. [download][Highlighted in the blog of the RSC]
12	Synthesis and Reactivity of Highly Nucleophilic Pyridines N. De Rycke, G. Berionni, F. Couty, H. Mayr, R. Goumont, O. R. P. David, Org. Lett. 2011, 13, 530-533. [download][Highly cited paper]
11	The N-Alkylation of Substituted 4-Tetrazolo[1, 5-a]pyridines: Easy Access to a New Series of Electrophiles G. Berionni, M. Branca, B. PÃ©got, J. Marrot, E. Kizilian, R. Goumont, Eur. J. Org. Chem. 2011, 26, 5104-5113. [download]
Publications 1-10 (Master and PhD work)	[See my Google Scholar profile]