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Publications

 

52

Manuscript under preparation


 

A. Osi, D. Mahaut, N. Tumanov, J. Wouters, B. Champagne, A. Chardon, G. Berionni, 2022


51

Manuscript under preparation


 

D. Mahaut, B. Champagne, G. Berionni, Catalytic Hydrogenations of Alkenes with Triptycene Based Frustrated Lewis Pairs, 2022


50

In progress

 

Special Issue in Synthesis, 2022

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49

Pub 49

Taming the Lewis Superacidity of Non-Planar Boranes: C-H Bond Activation and Non-Classical Binding Modes at Boron

A. Osi, D. Mahaut, N. Tumanov, L. Fusaro, J. Wouters, B. Champagne, A. Chardon, G. Berionni. Accepted, DOI 10.1002/anie.202112342

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48

Publi 48

Young Career Focus presents Guillaume Berionni, Synform, 2021, 159-161

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47

Publi 47



Future Prospects in Boron Chemistry: Boron Lewis Acids in Perspective

Chem. Syn. 2021, 1:10.

DOI: 10.20517/cs.2021.11


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46

Dam pub


Rational Development of a Metal-Free Bifunctional System for the C-H Activation of Methane: A Density Functional Theory Investigation

D. Mahaut, A. Chardon, L. Mineur, G. Berionni, B. Champagne, ChemPhysChem 2021, 22, 1958–1966.

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 45

 


Six-membered Rings with One Phosphorus Atom

F. Rammal, V. Magné, G. Berionni, S. Lakhdar, Comprehensive Heterocyclic Chemistry IV, Elsevier, 2022, Volume 7, 685-717 (book chapter).


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44




Four-membered Rings with One Phosphorus, Arsenic, Antimony, or Bismuth Atom

V. Magné, F. Rammal, G. Berionni, S. Lakhdar, Comprehensive Heterocyclic Chemistry IV, Elsevier, 2022, Volume 2, 335-362 (book chapter).


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43

Lei dalton

Sterically hindered ortho-substituted phosphatriptycenes as configurationally stable P-chirogenic triarylphosphines

L. Hu, D. Mahaut, N. Tumanov, J. Wouters, L. Collard, R. Robiette, G. Berionni, Dalton Trans. 2021, 50, 4772-4777

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42

Pub Math

Triptycene Boronates, Boranes, and Boron Ate‐Complexes: Toward Sterically Hindered Triarylboranes and Trifluoroborates

M. Gama, X. Antognini Silva, T-H. Doan, A. Osi, A. Chardon, N. Tumanov, J. Wouters, G. Berionni, Eur. J. Org. Chem. 2021, 1440–1445

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41

pub 41

Methylene Bridging Effect on the Structures, Lewis Acidities and Optical Properties of Semi Planar Triarylboranes

T.-H. Doan, A. Chardon, A. Osi, D. Mahaut, N. Tumanov, J. Wouters, B. Champagne, G. Berionni, Chem. Eur. J. 2021, 27, 1736-1743.

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40Syn

Non-planar Boron Lewis Acids Taking the Next Step: Development of Tunable Lewis Acids, Lewis Superacids and Bifunctional Catalysts

A. Chardon, A. Osi, D. Mahaut, A. Ben Saida, G Berionni, Synlett. 2020, 31, 1639-1648.

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39

Bora

Controlled Generation of 9-Boratriptycene by Lewis Adduct Dissociation: Accessing a Unique Non-Planar Triarylborane

A. Chardon, A. Osi, D. Mahaut, T.-H. Doan, N. Tumanov, J. Wouters, L. Fusaro, B. Champagne, G Berionni, Angew. Chem. Int. Ed. 2020, 59, 12402-12406.

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38

Pushing the Lewis Acidity Boundaries of Boron Compounds With Non-Planar Triarylboranes Derived from Triptycenes

A. Ben Saida, A. Chardon, A. Osi, N. Tumanov, J. Wouters, A. I. Adjieufack, B. Champagne, G. Berionni,  Angew. Chem. Int. Ed. 2019, 58, 16889–16893.

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37

Complementary Synthetic Approaches toward 9-Phosphatriptycene and Structure–Reactivity Investigations of Its Association with Sterically Hindered Lewis Acids

L. Hu, D. Mahaut, N. Tumanov, J. Wouters, R. Robiette, G. Berionni, J. Org. Chem. 2019, 84, 1126811274.

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36

 


The Halogen–Samarium Exchange Reaction: Synthetic Applications and Kinetics

L. Anthore‐Dalion, A. D. Benischke, B. Wei, G Berionni, P. Knochel, Angew. Chem. Int. Ed. 2019, 58, 4046.

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35

 

Opening Up New Research Lines in Lewis Acid/Base Catalysis

G. Berionni, L. Hu, A. Ben Saida, A. Chardon, M. Gama, A. Osi, D. Mahaut, X. Antognini Silva, Chimie Nouvelle, 2018, 128, 13.

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34 organolanthanum

Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles
A. D. Benischke, L. Anthore-Dalion, G. Berionni, P. Knochel, Angew. Chem. Int. Ed. 2017, 51, 16390-16394.
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33 allylation Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles
C. García-Ruiz, J. L.-Y. Chen, C. Sandford, K. Feeney, G. Berionni, H. Mayr, V. K. Aggarwal, J. Am. Chem. Soc., 2017, 139, 15324-15327.
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32 borylation

Mechanistic studies of formal thioboration reactions of alkynes
A. Issaian, D. J. Faizi, J. O. Bailey, P. Mayer, G. Berionni*, D. A. Singleton*, S. A. Blum*, J. Org. Chem. 2017, 82, 8165-8178.
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31 lithiathion Barbier continuous flow preparation and reactions of carbamoyllithiums for nucleophilic amidation
M. A. Ganiek, M. R. Becker, G. Berionni, H. Zipse, P. Knochel*, Chem. Eur. J. 2017, 23, 10280-10284.
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30 i_z0304 Nucleophilicities and Lewis basicities of sterically hindered pyridines
E. Follet, H. Zipse, S. Lakhdar, A. R. Ofial, G. Berionni*, Synthesis 2017, 49, 3495-3504. [special issue on the occasion of the 70th birthday of Professor Herbert Mayr]
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29 superelectophile Superelectrophilicity in Michael-Type Reactions: Water Addition to 4-Nitrobenzodifuroxan
S. Lakhdar,* G. Berionni*, F. Terrier,* Synthesis 2017, 49, 3453-3459. [special issue on the occasion of the 70th birthday of Professor Herbert Mayr]
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28 chem_toc Reactivity-tuning in frustrated Lewis pairs: nucleophilicities and lewis basicities of sterically hindered phosphines
E. Follet, P. Mayer, D. S. Stephenson, A. R. Ofial, G. Berionni*, Chem. Eur. J. 2017, 23, 7422-7427.
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27 fluorenyliums Structures, Lewis acidities, electrophilicities, and protecting group abilities of phenyl-fluorenylium and tritylium ions.
E. Follet, P. Mayer, G. Berionni*, Chem. Eur. J. 2017, 23, 623-630.
[download][Selected as hot paper]
26 zirconocenes Nucleophilicity of alkyl zirconocene and titanocene precatalysts and kinetics of activation by carbenium ions and by B(C6F5)3.
G. Berionni*, H. Kurouchi, L. Eisenburger, H. Mayr, Chem. Eur. J. 2016, 22, 11196-11200.
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25 frustrated_lewis Scope and mechanisms of frustrated Lewis pair catalyzed hydrogenation reactions of electron-deficient C=C double bonds
V. Morozova, P. Mayer, G. Berionni*, Angew. Chem. Int. Ed. 2015, 54, 14508-14512.
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24

indolylmethylium

Structure and Reactivity of Indolyl-methylium Ions: Scope and Limitations in Synthetic Applications
E. Follet, G. Berionni, P. Mayer, H. Mayr, J. Org. Chem. 2015, 80, 8643-8656.
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23 alkyl_ate_complexes Structure and Reactivity of Boron-Ate Complexes Derived from Primary and Secondary Boronic Esters
K. Feeney, G. Berionni, H. Mayr, V. K. Aggarwal, Org. Lett. 2015, 17, 2614-2617.
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22 boron_ate_complexes Fine-Tuning of the Nucleophilic Reactivities of Boron-Ate Complexes Derived From Aryl and Heteroaryl Boronic Esters
G. Berionni, A. I. Leonov, P. Mayer, A. R. Ofial, H. Mayr, Angew. Chem. Int. Ed. 2015, 54, 2780-2783.
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21 secondary_alkylithium Stereoselective Synthesis and Reactions of Secondary Alkyllithium Reagents Functionalized at the 3-Position
K. Moriya, D. Didier, M. Simon, J. M. Hammann, G. Berionni, K. Karaghiosoff, H. Zipse, H. Mayr, P. Knochel, Angew. Chem. Int. Ed. 2015, 54, 2754-2757.
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20 aromatic_radialenes Aromaticity evaluations of planar [6]radialenes
Guillaume Berionni*, Judy I. Chia Wu, Paul v R. Schleyer, Org. Lett. 2014, 16, 6116-6119
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19 hydride_donors Di- and Triarylmethylium Ions as Probes for the Ambident Reactivities of Carbanions Derived from 5-Benzylated Meldrum's Acid
X. Chen, Y. Tan, G. Berionni, A. R. Ofial, H. Mayr, Chem. Eur. J. 2014, 20, 11069-11077.
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18 tmpbases New In Situ Trapping Metalations of Functionalized Arenes and Heteroarenes with TMPLi in the Presence of ZnCl2 and Other Metal Salts
A. Frischmuth, M. Fernández, N. M. Barl, F. Achrainer, H. Zipse, G. Berionni, H. Mayr, K. Karaghiosoff, P. Knochel, Angew. Chem. Int. Ed. 2014, 53, 7928-7932.
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17 electrophilicity Mechanistic studies and quantification of the electrophilicity of aromatic triflones in sigma-complexation and SNAr reactions
N. El Guesmi, G. Berionni, B.H Asghar, J. Fluorine. Chem. 2014, 160, 41-47
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16 diastereoselectives

Diastereoselective Synthesis of Open-Chain Secondary Alkyllithium Compounds and Trapping Reactions with Electrophiles
G Dagousset, K Moriya, R Mose, G Berionni, K Karaghiosoff, P Knochel, Angew. Chem. Int. Ed. 2014, 53, 1425-1429.
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15 aromatic_substitution Electronic and solvent effects on kinetics of SNAr substitution reactions of substituted anilines with 2,6-bis(trifluoromethanesulfonyl)-4-nitroanisole
N. El Guesmi, G. Berionni, B.H Asghar, Monatsh. Chemie (Chemical Monthly) 2013, 144, 1537-1545.
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14 trifluorobates Electrophilic Aromatic Substitutions of Aryltrifluoroborates with Retention of the BF3- Group: Quantification of the Activating and Directing Effects of the Trifluoroborate Group
G. Berionni, V. Morozova, M. Heininger, P. Mayer, P. Knochel, H. Mayr, J. Am. Chem. Soc. 2013, 135, 6317-6324.
[download][Highlighted in Synfact, 2013, 9, 723]
13 nucleophilicity_scales Nucleophilicity parameters for designing transition metal-free C-C bond forming reactions of organoboron compounds
G. Berionni, B. Maji, P. Knochel, H. Mayr, Chem. Sci. 2012, 3, 878-882.
[download][Highlighted in the blog of the RSC]
12 super_dmap_organocatalysts Synthesis and Reactivity of Highly Nucleophilic Pyridines
N. De Rycke, G. Berionni, F. Couty, H. Mayr, R. Goumont, O. R. P. David, Org. Lett. 2011, 13, 530-533.
[download][Highly cited paper]
11 tetrazolopyridines The N-Alkylation of Substituted 4-Tetrazolo[1, 5-a]pyridines: Easy Access to a New Series of Electrophiles
G. Berionni, M. Branca, B. Pégot, J. Marrot, E. Kizilian, R. Goumont, Eur. J. Org. Chem. 2011, 26, 5104-5113.
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Publications 1-10 (Master and PhD work)



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