laboratoire de Réactivité et Catalyse Organique (RCO)

laboratoire de Réactivité et Catalyse Organique (RCO)

Presentation

Laboratory of Reactivity and Organic Catalysis (RCO, Professor Guillaume Berionni)

Team

Team

First group picture (October 2017) : First group meeting with a special guest : Prof. Alain Krief

Lei Hu – Guillaume Berionni  – Alain Krief – Ali Ben Saida

Publications


Publications 2010-
34 organolanthanum Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles
A. D. Benischke, L. Anthore-Dalion, G. Berionni, P. Knochel, Angew. Chem. Int. Ed. 2017, DOI, 10.1002/anie.201709553.
[download]
33 allylation Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles
C. García-Ruiz, J. L.-Y. Chen, C. Sandford, K. Feeney, G. Berionni, H. Mayr, V. K. Aggarwal, J. Am. Chem. Soc. 2017, DOI, 10.1021/jacs.7b10240.
[download]
32 borylation Mechanistic studies of formal thioboration reactions of alkynes
A. Issaian, D. J. Faizi, J. O. Bailey, P. Mayer, G. Berionni*, D. A. Singleton*, S. A. Blum*, J. Org. Chem. 2017, 82, 8165–8178.
[download]
31 lithiathion Barbier continuous flow preparation and reactions of carbamoyllithiums for nucleophilic amidation
M. A. Ganiek, M. R. Becker, G. Berionni, H. Zipse, P. Knochel*, Chem. Eur. J. 2017, 23, 10280–10284.
[download]
30 i_z0304 Nucleophilicities and Lewis basicities of sterically hindered pyridines
E. Follet, H. Zipse, S. Lakhdar, A. R. Ofial, G. Berionni*, Synthesis 2017, 49, 3495-3504. [special issue on the occasion of the 70th birthday of Professor Herbert Mayr]
[download]
29 superelectophile Superelectrophilicity in Michael-Type Reactions: Water Addition to 4-Nitrobenzodifuroxan
S. Lakhdar,* G. Berionni*, F. Terrier,* Synthesis 2017, 49, 3453-3459. [special issue on the occasion of the 70th birthday of Professor Herbert Mayr]
[download]
28 chem_toc Reactivity‐tuning in frustrated Lewis pairs: nucleophilicities and lewis basicities of sterically hindered phosphines
E. Follet, P. Mayer, D. S. Stephenson, A. R. Ofial, G. Berionni*, Chem. Eur. J. 2017, 23, 7422-7427.
[download]
27 fluorenyliums Structures, Lewis acidities, electrophilicities, and protecting group abilities of phenyl-fluorenylium and tritylium ions.
E. Follet, P. Mayer, G. Berionni*, Chem. Eur. J. 2017, 23, 623-630.
[download][Selected as hot paper]
26 zirconocenes Nucleophilicity of alkyl zirconocene and titanocene precatalysts and kinetics of activation by carbenium ions and by B(C6F5)3.
G. Berionni*, H. Kurouchi, L. Eisenburger, H. Mayr, Chem. Eur. J. 2016, 22, 11196-11200.
[download]
25 frustrated_lewis Scope and mechanisms of frustrated Lewis pair catalyzed hydrogenation reactions of electron-deficient C=C double bonds
V. Morozova, P. Mayer, G. Berionni*, Angew. Chem. Int. Ed. 2015, 54, 14508-14512.
[download]
24 indolylmethylium Structure and Reactivity of Indolyl-methylium Ions: Scope and Limitations in Synthetic Applications
E. Follet, G. Berionni, P. Mayer, H. Mayr, J. Org. Chem. 2015, 80, 8643-8656.
[download]
23 alkyl_ate_complexes Structure and Reactivity of Boron-Ate Complexes Derived from Primary and Secondary Boronic Esters
K. Feeney, G. Berionni, H. Mayr, V. K. Aggarwal, Org. Lett. 2015, 17, 2614-2617.
[download]
22 boron_ate_complexes Fine-Tuning of the Nucleophilic Reactivities of Boron-Ate Complexes Derived From Aryl and Heteroaryl Boronic Esters
G. Berionni, A. I. Leonov, P. Mayer, A. R. Ofial, H. Mayr, Angew. Chem. Int. Ed. 2015, 54, 2780-2783.
[download]
21 secondary_alkylithium Stereoselective Synthesis and Reactions of Secondary Alkyllithium Reagents Functionalized at the 3-Position
K. Moriya, D. Didier, M. Simon, J. M. Hammann, G. Berionni, K. Karaghiosoff, H. Zipse, H. Mayr, P. Knochel, Angew. Chem. Int. Ed. 2015, 54, 2754-2757.
[download]
20 aromatic_radialenes Aromaticity evaluations of planar [6]radialenes
Guillaume Berionni*, Judy I. Chia Wu, Paul v R. Schleyer, Org. Lett. 2014, 16, 6116-6119
[download]
19 hydride_donors Di- and Triarylmethylium Ions as Probes for the Ambident Reactivities of Carbanions Derived from 5-Benzylated Meldrum’s Acid
X. Chen, Y. Tan, G. Berionni, A. R. Ofial, H. Mayr, Chem. Eur. J. 2014, 20, 11069-11077.
[download]
18 tmpbases New In Situ Trapping Metalations of Functionalized Arenes and Heteroarenes with TMPLi in the Presence of ZnCl2 and Other Metal Salts
A. Frischmuth, M. Fernández, N. M. Barl, F. Achrainer, H. Zipse, G. Berionni, H. Mayr, K. Karaghiosoff, P. Knochel, Angew. Chem. Int. Ed. 2014, 53, 7928-7932.
[download]
17 electrophilicity Mechanistic studies and quantification of the electrophilicity of aromatic triflones in sigma-complexation and SNAr reactions
N. El Guesmi, G. Berionni, B.H Asghar, J. Fluorine. Chem. 2014, 160, 41-47
[download]
16 diastereoselectives Diastereoselective Synthesis of Open-Chain Secondary Alkyllithium Compounds and Trapping Reactions with Electrophiles
G Dagousset, K Moriya, R Mose, G Berionni, K Karaghiosoff, P Knochel, Angew. Chem. Int. Ed. 2014, 53, 1425-1429.
[download]
15 aromatic_substitution Electronic and solvent effects on kinetics of SNAr substitution reactions of substituted anilines with 2,6-bis(trifluoromethanesulfonyl)-4-nitroanisole
N. El Guesmi, G. Berionni, B.H Asghar, Monatsh. Chemie (Chemical Monthly) 2013, 144, 1537-1545.
[download]
14 trifluorobates Electrophilic Aromatic Substitutions of Aryltrifluoroborates with Retention of the BF3- Group: Quantification of the Activating and Directing Effects of the Trifluoroborate Group
G. Berionni, V. Morozova, M. Heininger, P. Mayer, P. Knochel, H. Mayr, J. Am. Chem. Soc. 2013, 135, 6317-6324.
[download][Highlighted in Synfact, 2013, 9, 723]
13 nucleophilicity_scales Nucleophilicity parameters for designing transition metal-free C-C bond forming reactions of organoboron compounds
G. Berionni, B. Maji, P. Knochel, H. Mayr, Chem. Sci. 2012, 3, 878-882.
[download][Highlighted in the blog of the RSC]
12 super_dmap_organocatalysts Synthesis and Reactivity of Highly Nucleophilic Pyridines
N. De Rycke, G. Berionni, F. Couty, H. Mayr, R. Goumont, O. R. P. David, Org. Lett. 2011, 13, 530-533.
[download][Highly cited paper]
11 tetrazolopyridines The N-Alkylation of Substituted 4-Tetrazolo[1, 5-a]pyridines: Easy Access to a New Series of Electrophiles
G. Berionni, M. Branca, B. Pégot, J. Marrot, E. Kizilian, R. Goumont, Eur. J. Org. Chem. 2011, 26, 5104-5113.
[download]


Publications 1-10 (Master and PhD work)



[See my Google Scholar profile]